Crystallography & Symmetry
patterns derived from their groups
Concept

Stacking fault — where it appears

A layer of a close-packed structure that sits in the wrong hollow, leaving the sequence of layers a word rather than a repeat. The crystal keeps a lattice within its layers and loses it across them, and the reflections that can see the layer shifts spread into streaks.

Named by 3 essays across 3 fields — each of them below, with the objects they name alongside it.

How many close packings there are of each period. Every cyclic sequence over three letters with no two adjacent alike is a close packing, and two sequences describe the same structure when one becomes the other by rotating the cycle, reversing it, or relabelling the three positions. Counting the classes that remain gives 1 of period 2, 1 of period 3, 1 of period 4, 1 of period 5, and 38 altogether up to period 10. Period two is hexagonal close packing and period three is cubic; everything above them is a polytype, equally dense and equally close packed, and silicon carbide has been found in more than two hundred of them. Nothing in the geometry chooses. What chooses is an energy difference of a few thousandths of an electron volt per atom, and no energies are computed here.

How many polytypes there are

One free choice per layer, repeated, gives a family of structures with the same composition, the same density and the same twelve neighbours — differing only in a sequence. Counting them up to rotation, reversal and relabelling turns "silicon carbide has hundreds of forms" into an enumeration.

applied · Packing One crystal, two rows: one streaks and one does not. Two rows of reflections from the same faulted crystal, at a fault rate of 0.05, each drawn against the same row from a perfect one. The upper row has h − k not divisible by three, so each layer contributes a different cube root of unity and the sequence of layers enters the sum: the sharp peaks collapse into a streak. The lower row has h − k divisible by three, the phase factor is one, every layer scatters in step, and the peaks are exactly as sharp as in the perfect crystal. The sorting is an integer condition — a reflection either can see the stacking or cannot, decided by h − k modulo three — which is the most direct evidence there is that the disorder is in the stacking and not in the layers. The profiles are averaged over 16 independently faulted crystals, because one crystal gives speckle rather than a diffuse profile.

The streaks a faulted stack makes

Close packing settles two directions and leaves the third to chance. A crystal that chooses wrongly now and then has a lattice in the plane of its layers and none across them — and its diffraction pattern says so, with some rows of spots as sharp as ever and others smeared into streaks, sorted by an integer condition.

diffraction · Diffraction One tile, two lattices. The smallest polyomino on exactly two lattices with no slide between them, of 5 cells. On the left its copies sit on one lattice and on the right on another, and neither tiling can be turned into the other by moving rows.

One tile, two lattices, and a row that slides

A crystal chooses its lattice, and it is natural to think a tile does too. Among all polyominoes to thirteen cells, more than five hundred that are not rectangles lie on more than one lattice, and some on seven. They fall into at most two families, and a family is a row of copies that can slide against the next row, which is exactly what makes polytypes possible in a real crystal. A tile with a prime number of cells has no such row unless it is a bar, and so it lies on at most two lattices.

classification · Isohedral

Named alongside it

The objects these essays reach for when they reach for this one.

PolytypeClose packingDiffuse scatteringDisorderIntegral breadthLattice tilingNecklace countingPolyominoRamsdell notationSpace groupStacking sequenceStructure factor

All concepts