Crystallography & Symmetry
patterns derived from their groups
Theme

The theme: Generated, not drawn

Every pattern on this site is the orbit of a motif under a group, and the group is then rediscovered from the drawing. A picture that was drawn by hand can have symmetries nobody intended.
The hexagonal lattice. Every periodic pattern in the plane repeats on one of five lattices. The classification is by which point symmetries the lattice itself admits, and the five are exhaustive — a sixth would need a rotation order no lattice can carry. Lattices

The lattice underneath

Strip a pattern of everything but its repeats and a grid of points is left. That grid is not decoration — it is the object that decides which symmetries the pattern is permitted to have.

 The angles between the faces of {102̅}. The form {102̅} of class 3̅m in section, with each face labelled by its indices. Its 6 faces make 15 pairs and only 3 distinct angles, the smallest being 76.43°. Every value is computed from the cell's metric — the one calculation in this family that is not integer arithmetic, because an angle is a real number and a lattice does not constrain it. Symmetry at work

Why a crystal face carries small whole numbers

A crystal face is flat because it lies on a plane of lattice points, and its orientation is therefore named by three integers rather than by two angles. That the integers exist is a theorem about lattices; that they are usually smaller than four is a separate claim about growth, and the two are routinely run together.

 The seventeen wallpaper groups. Every way of repeating a pattern across the plane, one cell of each. Each tile was generated from its group's operations and then examined independently to confirm it has exactly those symmetries and no others. The classification

The seventeen

Every way of repeating a pattern across a flat surface, exhibited rather than tabulated. The number is a theorem with a finite proof, and the proof is walkable in an afternoon.

 The thirty-two crystal classes. Every crystallographic point group, as a stereogram. Each was found by enumerating the subgroups of m3̅m and of 6/mmm, and each diagram is the orbit of one general direction under the group, filled where the pole is in the upper hemisphere and open where it is in the lower — which is the only thing in the picture that tells a rotation from a rotoinversion. What symmetry decides

Thirty-two, and no others

There are exactly thirty-two ways a crystal can be symmetric about a point. Not thirty-two that anybody has catalogued — thirty-two that a finite search produces, from two starting groups, with every step of the reduction counted separately so that no two of them can quietly compensate.

 A rotation. The motif in the first colour, its images under a single rotation in the second, and the symmetry element marked where the operation itself says it lies. Operations

What a symmetry actually is

Not a property of a shape but a motion that leaves it alone. Once symmetry is a verb rather than an adjective, everything else in the subject follows — including why there can only ever be seventeen wallpapers.

 A glide. The motif in the first colour, its images under a single glide in the second, and the symmetry element marked where the operation itself says it lies. Operations

The four motions of the plane

Slide, turn, flip, and the odd fourth thing that is a flip and a slide together but neither on its own. Every symmetry of every flat pattern that has ever been made is one of these.

 The round trip, on Pnma. 8 operations were generated from the standard generators of Pnma; the orbit of three points in general position was formed, the group was discarded, and 8 operations were rediscovered from the 24 points alone. The two sets are identical, which is what the figure asserts. Into space

Forgetting a group in three dimensions

For three phases this site said its machinery was two-dimensional and decided nothing about a space group. That was true, and it was a limit rather than a principle — nothing in the decidability argument mentions the number two.

 The wallpaper group p3m1. A pattern with the symmetry of p3m1, generated by applying the group's 6 operations to an asymmetric motif and repeating across the lattice. The symmetries of the result were then found independently and match the group exactly. The classification

p3m1 and p31m

Two groups with the same lattice, the same point group and the same number of operations, differing only in where the mirrors sit. The pair is the clearest evidence that position is as much a part of a symmetry as presence.

 The translation of every operation, split in two. Every operation of P2, P2₁, Pm and Pc other than the identity, with its translation split into the intrinsic part — one n-th of the sum of the operation applied to itself n times, which no choice of origin can remove — and the location part, which is only a statement about where the origin was put. 2 of the 4 operations shown have a non-zero intrinsic part, and those are exactly the screws and the glides. Into space

The half of a translation that is not a choice

Every operation's translation splits in two — a part that belongs to the operation and a part that only records where somebody put the origin. Almost everything peculiar about space groups is a consequence of that split, including why there are two hundred and thirty rather than seventy-three.

 The phase problem. The same structure rebuilt from its diffraction three ways: with the true amplitudes and phases, with the phases scrambled, and with the amplitudes discarded but the phases kept. The atoms survive the loss of the amplitudes and do not survive the loss of the phases, which is what an experiment throws away. How it is known

The phase problem

A detector records how much light arrives and not when it arrives, so half of every diffraction measurement is thrown away before it is written down. The half that is lost turns out to be the half that carries the structure.

 Doing one after another. Two symmetries of a pattern, and the one that doing both lands on. The third picture is not a new operation drawn to fit — it is the composition, and it was already in the group. Operations

Why it is a group and not a list

The symmetries of a pattern cannot be chosen independently. Do two of them in succession and the result is forced to be a third, which is why there is no eighteenth wallpaper for anybody to invent.

 The tile does not force aperiodicity — the decoration does. A rhomb with the acute angle of a Penrose tile, repeated by the lattice its own edges generate. The tiling is periodic, so the shape forbids nothing. Adding the edge decoration changes the answer: every interior edge of this tiling presents a double arrow against a single one, which the matching rule refuses. Order without repetition

Matching rules, and what actually forces aperiodicity

The two Penrose rhombs are usually said to tile the plane only aperiodically. They tile it periodically without difficulty. What cannot be done periodically is tiling them according to the decoration, and the distinction is the whole result.

 Why p4 cannot be drawn with dots. The same group applied to a single dot and to a motif with no symmetry of its own. The dot's orbit turns out to have more symmetries than the group it was made with, so a figure drawn that way illustrates a different group from the one in its caption. The classification

The motif must be a comma

A dot is too symmetric to illustrate most wallpaper groups. Its orbit acquires mirrors nobody asked for, and the resulting figure is quietly of a different group from the one in its caption.

 Growing the p4 orbit. One motif, then more of the group's operations applied to it, until applying another produces nothing new. The pattern is the orbit; the drawing is only its shadow. Operations

The orbit is the pattern

A wallpaper is not designed and then found to have symmetry. It is the set of places a group sends a single mark, and once that is taken literally the pattern can be grown, checked, and caught out.

 The seven frieze groups. Every way of repeating a motif along a strip. Seven, and no more: the only ingredients are a translation, a mirror across the strip, a mirror along it, a half-turn and a glide, and most combinations of those turn out to generate one another. The classification

Seven friezes

The same classification argument on a strip instead of a plane, where it is short enough to check by hand. Seven ways to repeat a motif along a line, with names like hop, step and sidle.

 The crystal classes 3m, 3̅m, 6̅2m. 3m, 3̅m, 6̅2m: the orbit of a general direction under each group, giving 6, 12, 12 poles, with general positions and symmetry elements. Filled marks are poles above the plane of the page and open ones below it. What symmetry decides

3m1 and 31m are one class

This site has an essay arguing that p3m1 and p31m are genuinely different groups. As point groups the same two objects are one class — and the two subgroups are each normal in the hexagonal holohedry, so nothing in the lattice relates them. What does is a rotation of thirty degrees.

 p3, twinned. p3 twinned by a rotation. To the left of the composition line the motif sits where p3 puts it; to the right every copy has been carried over by the twin law, which is one of the 3 operations the hexagonal lattice has and p3 does not. 24 images on the left, 24 on the right, and the lattice runs through the line unbroken — which is exactly why a twinned crystal looks like a single one. Symmetry at work

A twin is a symmetry the lattice has and the crystal does not

Two orientations of one structure, grown together across a boundary the lattice runs straight through. The operation relating them cannot be a symmetry of the crystal, or there would be nothing to see, and it must be a symmetry of the lattice, or the boundary would be a crack — which leaves exactly a coset, and a short computable list.

 A conjugacy class of p4m. One conjugacy class of p4m drawn in place: every copy of the same symmetry that the group can carry onto every other. Conjugation was applied to each of the 8 operations by each of them in turn, and the kind and order of the result was checked to match every time. Operations

The same symmetry, somewhere else

Two mirrors in a pattern can be the same symmetry or two different ones, and looking will not settle it. Conjugation is the operation that decides, and it turns an intuition about sameness into arithmetic.

 Special positions in p4m. Every point of a 12×12 grid inside the cell of p4m, drawn at a size set by how many operations fix it. 80 of the 144 are general — nothing but the identity leaves them alone, so their orbit is the full 8 points. The other 64 are special, and fall into 3 kinds: 60 points fixed by 2 operations, with orbits of 4; 2 points fixed by 4 operations, with orbits of 2; 2 points fixed by 8 operations, with orbits of 1. Operations

The points a group treats differently

Almost every point of a cell has an orbit as long as the group. The exceptions are the points some operation leaves alone, and they are where atoms sit, where a structure's formula comes from, and where a careless motif destroys the group it was meant to illustrate.

 Centring the five lattices. Each of the five plane lattices with the midpoint of every cell added, and the type of lattice that results — read off the reduced basis of the new point set rather than looked up. Every centring halves the cell area, so the original lattice is a sublattice of index two in the centred one, and every centred lattice is again one of the five. Two of the five come back as themselves and are therefore no richer for being centred. The rectangular and rhombic lattices exchange, which is what makes them one family under two descriptions. And the hexagonal lattice centred is rectangular — its holohedry falls from 12 to 4, so centring destroys the symmetry it was meant to display. Lattices

Centring, counted as a sublattice

Adding the centre of every cell to a lattice produces another lattice, containing the first with index two. Doing it to each of the five in turn shows why the list is five rather than ten, and why only one of the five has a centred description worth keeping.

 A fundamental domain for p4m. One representative from every orbit of p4m, shaded, with the images that tile the rest of the cell. The domain was found by computing orbits rather than by drawing a region, and every sample's orbit was checked to meet it exactly once — so the region has neither a gap nor an overlap. Operations

The fundamental domain

The smallest piece of a pattern from which the group rebuilds the rest. Drawing one is easy and drawing one correctly is not, because a region with a gap or an overlap looks exactly like a region without.

 The seventeen sorted by lattice: 2, 5, 2, 3, 5. The five plane lattices, each drawn from the basis every other figure here uses, with the wallpaper groups that sit on it and the order of each against its lattice's holohedry. The counts are 2, 5, 2, 3, 5, which is seventeen again, arrived at by a different route from the case analysis on rotation order. Two relations hold and both are checked. Every group's order divides its lattice's holohedry, because an operation has to map the lattice onto itself before it can map the pattern onto itself — which is why a quarter turn has nowhere to live but a square lattice. And the converse fails on every one of the five: each lattice carries at least one group whose order falls short of what the lattice offers, so knowing the lattice narrows the group to a handful of candidates and never to one. The pairs printed in the accent colour are the groups that take everything their lattice permits. The classification

The classification proof, one branch at a time

Seventeen is a theorem, and the argument that establishes it is a finite case analysis that fits on a few pages. Working through it is the difference between knowing the number and knowing why there is no eighteenth.

 The substitution, 6 generations. The rule "every long tile becomes a long and a short, every short tile becomes a long", applied 6 times from a single tile. Each generation is as long as the previous two together, so the tile counts are Fibonacci numbers — 13 long and 8 short at the last row — and their ratio is 1.62500 against the golden ratio's 1.61803. The sequence never repeats and every finite piece of it recurs infinitely often, which is order without periodicity in its smallest form. Order without repetition

The smallest quasicrystal

Two tile lengths on a line, in the golden ratio, in a sequence that never repeats. Three completely different constructions produce it, they are required here to agree, and its diffraction needs two integers per peak where a periodic chain needs one.

 The 4₁ screw axis. 1 of the eleven screw axes a lattice permits, each drawn as the helix it is: 4₁. A turn of 2π/n followed by an advance of m/n of the repeat, so that n turns land exactly m cells along. 0 of those drawn are its own mirror image; the rest come in left- and right-handed pairs. Into space

Turning and climbing at once

A rotation has a fixed point and a screw has none. That sounds like a small difference and it is the reason a space group is not a point group with extra letters, the reason two hundred and thirty is not seventy-three, and the reason a helix can be a crystal.

All themes · All essays