Crystallography & Symmetry
patterns derived from their groups
Generator

p4: one hand only

p4: one hand only
p4: one hand only. The standard motif — three points in no particular arrangement — repeated by p4, with each copy coloured by the sign of the area of the triangle it makes. Every copy has the same sign, because every operation of this group preserves orientation. A structure built from one enantiomer can sit here. The colours were computed from the coordinates rather than assigned.

The standard motif — three points in no particular arrangement — repeated by p4, with each copy coloured by the sign of the area of the triangle it makes. Every copy has the same sign, because every operation of this group preserves orientation. A structure built from one enantiomer can sit here. The colours were computed from the coordinates rather than assigned.

12 essays call one-hand. The drawing above is what it returns with no arguments at all; every call below passes it something, because a placement that passes nothing draws whichever member of the family the generator happens to default to rather than the one its essay argues about. Every one of this site's 522 essays names its parameters at the call site, which the standard pass of 2026-08-09 established and param-floor holds.

Where it is called

Changing this generator changes every one of these figures.

P222: 16 descriptions of one structure. P222 has 4 operations in a cell. 8 origins leave every one of them exactly where it was, and 8 linear parts of the lattice's holohedry normalise the group, so its Euclidean normaliser has 64 elements per cell and the index is 16. That index is the number of coordinate lists that describe one and the same arrangement of atoms. Each was applied to a motif and the resulting point sets compared: the numbers differ and the sets are identical, which is the check that makes the count mean anything. Operations

One crystal, and sixteen coordinate lists

Two structure reports can disagree in every number and describe the same arrangement of atoms, because a space group does not fix its own origin or its own axes. How many genuinely different lists there are is the index of the group in its Euclidean normaliser — a number, computable, and the thing a structural database has to divide out before it can say two entries are the same compound.

 p4m: 4 and 4. The standard motif — three points in no particular arrangement — repeated by p4m, with each copy coloured by the sign of the area of the triangle it makes. 4 copies have one sign and 4 the other, because the group contains an operation that reverses orientation. A structure built from one enantiomer cannot sit here: the group would put its mirror image in the same crystal. The colours were computed from the coordinates rather than assigned. Into space

The groups a single hand may sit in

A protein is built from one enantiomer of every amino acid, and a crystal of it contains nothing else. That single fact deletes most of the classification at a stroke: any operation reversing orientation would put the other hand in the same crystal. The criterion is one line of arithmetic, and in the plane the enumeration is complete — five of the seventeen.

 4_1: which index gives which group. The isomorphic subgroups of a 4₍1₎ screw group, index by index. An index sharing a factor with 4 gives nothing — the translation cannot be written on the new cell at all — and the rest give a screw whose index is the old one times the inverse of p modulo the axis order. So the answer alternates: some indices give the group back and others give its mirror image, and which is which is decided by p modulo the order of the axis. Into space

A bigger cell, and sometimes the mirror

An isomorphic subgroup gives up nothing but scale — the same group again on a coarser lattice. In space the screw axes sharpen the question, and the answer contains a surprise: a cell three times taller holds the group's enantiomorphic partner, so a left-handed screw contains a right-handed one with nothing done to the crystal but a change of description.

 Unreflected copies stop at 1 ring. Copies of the hat, all of the same handedness, covering a core of 1 ring of hexagons — 9 tiles, every cell covered once. At 2 rings the same search runs to exhaustion and returns nothing: there is no such covering, and the failure is a proof for that region rather than a search that gave up. The reflected copy is not a convenience of the drawing; the tiling cannot proceed without it. Order without repetition

The tile that needs no reflection

One shape tiles the plane and never repeats, and it does it with copies of both hands. Cut the tiles out of card and that is nothing; ask for it in a molecule, where handedness cannot be undone by turning something over, and it is the whole question.

 A triangle sliding from one mirror to another. Two vertices fixed and the third slid along a line. At the left end the triangle is isoceles about the vertical, at the right end it is isoceles about a different line, and both ends have a mirror — so the measure is exactly zero at both, by cancellation rather than by a search running out. Between them the triangle has no mirror at all and the measure rises to 0.0422. The faint curve is the handedness over the same family, which is a different quantity: it has a sign, it is largest where the measure is not, and it does not vanish at either end. Into space

How chiral, as a number

A group answers one bit: a set either has an improper symmetry or it does not. Two shapes can both be chiral and one of them be a mirror-symmetric thing with a substituent out of place while the other is a helix, and nothing in the classification says which is which. A distance does.

 One achiral motif in p4, chiral along one line and achiral along two. The same motif — three points with a mirror and no other symmetry — repeated by p4, the plane group of quarter-turns with no mirror, and placed with its mirror along three different lines of the square lattice. Along the first line the pattern has no operation that reverses orientation: it is chiral, although every piece of it is achiral. Along the second and third the motif's mirror is also a mirror of the whole pattern, and the detected groups are p4m and p4g; the mirror lines of each pattern are drawn. All three verdicts come from detecting the symmetry of the points and agree with whether the motif's mirror normalises p4. Into space

A hand made of pieces that have none

Quartz is built from tetrahedra that have no handedness, and every quartz crystal is left-handed or right-handed anyway. Put a piece with a mirror into a pattern whose group has none, and the pattern keeps the piece's mirror only if that mirror lies on one of a few lines the group's normaliser draws. Anywhere else, the arrangement has a hand its parts do not.

 Seventeen plane groups, and one chiral sheet over each. The seventeen plane groups, whether each is chiral as a pattern in the plane, how many sheets can be built over it by giving each operation a sign on the sheet's normal — 80 in all — and which of those sheets is chiral in space. There is always exactly one. For the five groups chiral in the plane it is the sheet whose two faces differ and nothing turns it over. For the twelve achiral in the plane it is the sheet turned over by exactly the operations that reverse orientation in the plane, so that every mirror line becomes a half-turn axis lying in the sheet. Into space

Chiral in the plane is not chiral in the room

A pattern with mirrors all over it can be a sheet with a hand, and a pattern with no mirror can be a sheet without one. Whether a layer is chiral depends on what each of its operations does to the side of the sheet, and over every one of the seventeen plane groups exactly one sheet is chiral in space.

 A thread's two signs, and the four kinds of operation. Every operation of a rod group carries the axis to itself, so it does two independent things: it keeps or reverses the direction along the thread, by a sign σ, and it keeps or reverses the handedness of the plane across the thread, by the determinant of a 2 × 2 matrix. The determinant in space is the product, so the shaded cells are the proper operations — a turn or screw about the axis, and a half-turn crossing it — and the unshaded ones are the improper. A rod group is chiral when all of its operations sit on the shaded diagonal, and polar along its axis when all of them sit on the top row. The two conditions pick out different diagonals of the same square, which is why neither implies the other. Into space

A thread's hand is not a choice

A sheet's handedness in space depends on a sign that the plane pattern does not fix, so one plane group carries several sheets and exactly one of them is chiral. A thread has no such freedom: 32 of the 75 rod groups are chiral, they sit over 9 of the 27 axial classes, and which they are is settled before any structure is drawn. Only its direction depends on how the class lies along it.

 The seven edges a sheet can have. The seven frieze groups drawn as the profile of a cut edge: along the strip is along the edge, up the strip is the sheet's normal, and the half-sheet itself stretches away from the viewer. Each is labelled with what its operations are in the sheet — a mirror standing across the edge, a mirror or glide in the sheet's own plane, a half-turn about the cut's in-plane normal — and with how many of the eighty layers have it as the edge in some direction. Only p1 and p2 have no mirror image among their operations, so only they are chiral edges; every one of the seven occurs. Into space

Cutting a sheet can give it a hand

Cut a periodic sheet along a line and the edge that is left has a symmetry of its own: a frieze group, drawn in the plane across the cut. A chiral sheet can only have chiral edges. An achiral one usually has chiral edges too, in all but a few directions — and eight of the eighty layer groups have no achiral edge at all, however the sheet is cut.

 Two cuts that give back the mirror a single cut takes away. A sheet whose only symmetry beyond translation is a centre of inversion: each flag has a copy turned half round and moved to the underside, drawn open, and the dots are the centres. Every single cut leaves a chiral edge, and the piece on the far side carries its mirror image. The upper ribbon is cut symmetrically about a row of centres, so each centre on its middle line carries the ribbon onto itself with its two edges exchanged, and the ribbon is achiral. The lower ribbon, cut at the same width about a line with no centre on it, keeps nothing but translations and is chiral. Into space

A ribbon can be achiral where its edges are not

Cut an achiral sheet once and the edge is usually chiral, in almost every direction. Cut it twice, into a ribbon, and the ribbon may be achiral even when both its edges are chiral, because an operation can carry the ribbon onto itself by exchanging the edges — but only if the ribbon's middle line sits on a centre of inversion or a mirror parallel to the cut. Seven of the eight sheets with no achiral edge give achiral ribbons, and one achiral sheet gives nothing but chiral strips however it is cut.

 Thirty-one band groups from three signs. Every operation of a ribbon keeps or reverses the direction along it, the direction across it and the sheet's two faces, so its point group is a subgroup of the eight sign triples. Each operation that keeps the along-direction can also carry half a period along the ribbon, a glide or a screw, and the choice must be consistent. The sixteen subgroups, weighted by their consistent choices, give 1 + 10 + 16 + 4 = 31, the number of band groups, and the enumeration finds all 31 as distinct groups. Into space

Every band group is a ribbon

A ribbon cut from a sheet has a symmetry group with translations along one direction only, one of 31 band groups. The 31 can be counted from three signs: whether an operation reverses the ribbon's direction, its width, or the sheet's faces, and whether it slides half a period. Cutting the eighty layers every way reaches all 31, seven of them as single edges and twenty-four only as ribbons cut symmetrically about a special line. Five of those twenty-four have no improper operation at all.

 Where the four-fold screws of one crystal cross a plane. A space group of the body-centred class I4/m that has a centre of symmetry, seen along the direction of its four-fold axes: the points where the special lines along that direction cross a plane, over four cells of the projection. A rod cut along the large filled lines is p4₃, a four-fold screw of one hand; along the other large lines, p4₁, its mirror image. The crystal's centre of symmetry carries each kind onto the other, so both are there and neither hand is favoured. Into space

A crystal with no hand holds rods of both hands

Rolling a flat pattern into a tube reaches fifty-four of the seventy-five rod groups and never a screw that comes in a pair of hands. Cutting a column out of a crystal reaches all seventy-five. Sixteen of them are handed screws, and half of those can be cut from a crystal that has a centre of symmetry, from a line that happens to be a screw of one hand, with its mirror image a short distance away. A handed thread does not need a handed crystal, only a handed place in one.

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