Crystallography & Symmetry
patterns derived from their groups
Concept

Curie principle — where it appears

That the symmetry of an effect contains the intersection of the symmetries of its causes. Applied to a crystal in a field it gives a subgroup of the crystal's class, which then decides by Neumann's principle what the material in the field is permitted to do.

Named by 3 essays across one field — each of them below, with the objects they name alongside it.

The seven groups a uniform field can have. Five of them have an axis and two do not. A cone has every rotation about its axis and mirrors containing it; a cylinder adds the mirror across the axis and the two-folds that go with it; turning either one destroys the mirrors that would reverse the turn. The sphere and the sphere made of something with a handedness are the two with no axis to speak of. Each drawing is the definition: the group is the set of motions leaving the picture unchanged.

The seven groups a field can have

Every group in this collection so far has been finite, because a lattice forbids the alternatives. A uniform field has no lattice: rotate it about its own axis through any angle at all and nothing has changed. There are exactly seven such groups, and they come out of the same closure argument that turns sixteen frieze candidates into seven.

point-groups · Curie What a crystal keeps of itself in a field. Each class, with what is left of it when a field is applied along the axis of its own setting. The residual is the intersection of the class with the field's own group, computed on matrices and matched against the thirty-two rather than named by hand. Where the residual is the class itself, the field takes nothing away — and for an electric field those are exactly the polar classes.

What a crystal keeps in a field

Curie's principle says the symmetry of an effect contains the intersection of the symmetries of its causes. Applied to a crystal in a field that is an intersection of two groups, one of them infinite — and it comes out exactly, class by class, as a subgroup that decides which effects are permitted next.

point-groups · Curie A looser fibre with more longitudinal response. The three piezoelectric coefficients of a polar fibre of grains with d33 = 90, d31 = −33 and d15 = 560 pC/N, as the tilt spread grows from nothing to a uniform one, with the degree-one and degree-three parts of d33 dashed. The degree-one part is 265 and the degree-three part -175; the negative octupole decays faster, so d33 rises from 90 to 168 at a spread of 30° before falling to nothing.

A looser fibre, more piezoelectric

Spread the grains of a fibre about its axis and every property decays, but not at one rate: each spherical harmonic a property is built from is multiplied by its own average, and the higher the degree the faster it goes. A property made of two degrees therefore changes shape as the fibre loosens. For a polar grain whose shear coefficient dwarfs its longitudinal one, the fibre's longitudinal response nearly doubles before it falls; for another, a shear coefficient changes sign.

point-groups · Curie

Named alongside it

The objects these essays reach for when they reach for this one.

Limiting groupAxial vectorCrystal classNeumann principlePermissionPolar vectorAnisotropyClosureDomain stateFerroelectricityInfinite groupIntersection

All concepts